Light-Infused Hybrid Particles Speed Energy Transfer in Organic Semiconductors
- on May 07, 2022
Polaritons offer the best of two very different worlds. These hybrid particles combine light and molecules of organic material, making them ideal energy transfer vessels in organic semiconductors. They are both compatible with modern electronics but also move speedily, thanks to their photonic origins.
However, polaritons are difficult to control, and much of their behavior is a mystery.
A project led by Andrew Musser, assistant professor of chemistry and chemical biology in the Cornell University College of Arts and Sciences, has found a way to tune the speed of this energy flow. This “throttle” can move polaritons from a near standstill to something approaching the speed of light and increase their range – an approach that could eventually lead to more efficient solar cells, sensors, and LEDs.
The team’s paper, “Tuning the Coherent Propagation of Organic Exciton-Polaritons through Dark State Delocalization,” was published on April 27, 2022, in the journal Advanced Science. The lead author is Raj Pandya of the University of Cambridge.
Over the last several years, Musser and colleagues at the University of Sheffield have explored a method of creating polaritons via tiny sandwich structures of mirrors, called microcavities, that trap light and force it to interact with excitons – mobile bundles of energy that consist of a bound electron-hole pair.
They previously showed how microcavities can rescue organic semiconductors from “dark states” in which they don’t emit light, with implications for improved organic LEDs.
For the new project, the team used a series of laser pulses, which functioned like an ultrafast video camera, to measure in real time how the energy moved within the microcavity structures. But the team hit a speedbump of their own. Polaritons are so complex that even interpreting such measurements can be an arduous process.
“What we found was completely unexpected. We sat on the data for a good two years thinking about what it all meant,” said Musser, the paper’s senior author.
Eventually the researchers realized that by incorporating more mirrors and increasing the reflectivity in the microcavity resonator, they were able to, in effect, turbocharge the polaritons.
“The way that we were changing the speed of the motion of these particles is still basically unprecedented in the literature,” he said. “But now, not only have we confirmed that putting materials into these structures can make states move much faster and much further, but we have a lever to actually control how fast they go. This gives us a very clear roadmap now for how to try to improve them.”
In typical organic materials, elementary excitations move on the order of 10 nanometers per nanosecond, which is roughly equivalent to the speed of world-champion sprinter Usain Bolt, according to Musser.
That may be fast for humans, he noted, but it is actually quite a slow process on the nanoscale.
The microcavity approach, by contrast, launches polaritons a hundred-thousand times faster – a velocity on the order of 1% of the speed of light. While the transport is short lived – instead of taking less than a nanosecond, it’s less than picosecond, or about 1,000 times briefer – the polaritons move 50 times further.
“The absolute speed isn’t necessarily important,” Musser said. “What is more useful is the distance. So if they can travel hundreds of nanometers, when you miniaturize the device – say, with terminals that are 10’s of nanometers apart – that means that they will go from A to B with zero losses. And that’s really what it’s about.”
This brings physicists, chemists and material scientists ever closer to their goal of creating new, efficient device structures and next-generation electronics that aren’t stymied by overheating.
“A lot of technologies that use excitons rather than electrons only operate at cryogenic temperatures,” Musser said. “But with organic semiconductors, you can start to achieve a lot of interesting, exciting functionality at room temperature. So these same phenomena can feed into new kinds of lasers, quantum simulators, or computers, even. There are a lot of applications for these polariton particles if we can understand them better.”
Reference: “Tuning the Coherent Propagation of Organic Exciton-Polaritons through Dark State Delocalization” by Raj Pandya, Arjun Ashoka, Kyriacos Georgiou, Jooyoung Sung, Rahul Jayaprakash, Scott Renken, Lizhi Gai, Zhen Shen, Akshay Rao and Andrew J. Musser, 27 April 2022 , Advanced Science.
Co-authors include Scott Renken, MS ’21 of the Musser Group; and researchers from the University of Cambridge, the University of Sheffield and Nanjing University.
The research was supported by the Engineering and Physical Sciences Research Council in the United Kingdom, the University of Cambridge and the U.S. Department of Energy.